(Acetylacetonato) dicarbonylrhodium(I)

Categories : Rhodium (Rh) Catalysts, Inorganic Chemistry and Catalysis, Chemical Synthesis, Catalysts, Catalysis, Materials Science, Solution Deposition Precursor.

Applications :

(Acetylacetonato)dicarbonylrhodium(I) can be used as a catalyst for

1) Hydroformylation of olefins [Ref: Synthesis, 2001, 1; Org. Lett., 2009, 11, 2659]

2)  Silylformylation of olefins [Ref: J. Am. Chem. Soc., 1997, 119, 12416]

3) Carbonylative silylcarbo-cyclization in the syntheses of isodomoic acids [Ref: J. Am. Chem. Soc., 2009, 131, 14188]

4) Conjugate addition of aryl- and alkenylboronic acids to enones [Ref:  Organometallics, 1997, 16, 4229; Org. Lett., 2009, 11, 971]