Chloro(1,5-cyclooctadiene)rhodium(I) dimer

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Description

Chiralyst P493, 1,5-Cyclooctadienerhodium(I) chloride dimer, Bis(1,5-cyclooctadiene)dirhodium(I) dichloride, Chloro(1,5-cyclooctadiene)rhodium(I) dimer, Di(μ-chloro)bis(1,5-cyclooctadiene)dirhodium(I), Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]dirhodi

Chloro(1,5-cyclooctadiene)rhodium(I) dimer is a precursor to several Rh containing catalysts and an efficient hydrogenation catalyst

Categories : Rhodium (Rh) Catalysts, Inorganic Chemistry and Catalysis, Chemical Synthesis, Catalysts, Catalysis

Applications : Chloro(1,5-cyclooctadiene)rhodium(I) dimer is used as a catalyst for: 

  • Dehydrogenation of hydrogen storage materials such as ammonia-borane [Ref: Inorganic Chemistry 46(18), 7522-7527, (2007)]
  • Ring-opening polymerization [Ref: Science 330(6000), 66-69, (2010)]
  • Hdroformylation reaction of olefins [Ref: New. J. Chem. 27(2), 227-229, (2003)]

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