Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)

Categories : Ruthenium (Ru) Catalysts, Inorganic Chemistry and Catalysis, Chemical Synthesis, Catalysts, Catalysis

Applications:

Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) severs as a catalyst for:

1) Alcohol α-allylation with dienes or allenes under transfer hydrogenation conditions [Ref:  J. Am. Chem. Soc., 2008, 130, 6338; J. Am. Chem. Soc., 2011, 133, 1141]

2) Tandem isomerization (to imine), followed by Friedel Crafts alkylation [Ref: 3. J. Am. Chem. Soc., 2008, 130, 14453]

3)  Amination of alcohols with ammonia [Ref: Angew. Chem. Int. Ed., 2011, 50, 7599]